:: wikimiki.org ::

Ultraviolet

Ultraviolet

Ultraviolet (UV) radiation is electromagnetic radiation of a wavelength shorter than that of the visible region, but longer than that of soft X-rays. It can be subdivided into near UV (380–200 nm wavelength), far or vacuum UV (200–10 nm; abbrev. FUV or VUV), and extreme UV (1–31 nm; abbrev. EUV or XUV). When considering the effect of UV radiation on human health and the environment, the range of UV wavelengths is often subdivided into UVA (380–315 nm), also called Long Wave or "blacklight"; UVB (315–280 nm), also called Medium Wave; and UVC (< 280 nm), also called Short Wave or "germicidal". See 1 E-7 m for a list of objects of comparable sizes. In photolithography, in laser technology, etc., the term deep ultraviolet or DUV refers to wavelengths below 300nm. The name means "beyond violet" (from Latin ultra, "beyond"), violet being the color of the shortest wavelengths of visible light. Some of the UV wavelengths are colloquially called black light, as it is invisible to the human eye. Some animals, including birds, reptiles, and insects such as bees, can see into the near ultraviolet. Many fruits, flowers, and seeds stand out more strongly from the background in ultraviolet wavelengths as compared to human color vision. Many birds have patterns in their plumage that are invisible at usual wavelengths but seen in ultraviolet, and the urine of some animals is much easier to spot with ultraviolet. The Sun emits ultraviolet radiation in the UVA, UVB, and UVC bands, but because of absorption in the atmosphere's ozone layer, 99% of the ultraviolet radiation that reaches the Earth's surface is UVA. (Some of the UVC light is responsible for the generation of the ozone.) Ordinary glass is transparent to UVA but is opaque to shorter wavelengths. Silica or quartz glass, depending on quality, can be transparent even to vacuum UV wavelengths. The onset of vacuum UV, 200 nm, is defined by the fact that ordinary air is opaque below this wavelength. This opacity is due to the strong absorption of light of these wavelengths by oxygen in the air. Pure nitrogen (less than about 10 ppm oxygen) is transparent to wavelengths in the range of about 150–200 nm. This has wide practical significance now that semiconductor manufacturing processes are using wavelengths shorter than 200 nm. By working in oxygen-free gas, the equipment does not have to be built to withstand the pressure differences required to work in a vacuum. Some other scientific instruments, such as circular dichroism spectrometers, are also commonly nitrogen purged and operate in this spectral region. Extreme UV is characterized by a transition in the physics of interaction with matter: wavelengths longer than about 30 nm interact mainly with the chemical valence electrons of matter, while wavelengths shorter than that interact mainly with inner shell electrons and nuclei. The long end of the EUV/XUV spectrum is set by a prominent He⁺ spectral line at 30.4nm. XUV is strongly absorbed by most known materials, but it is possible to synthesize multilayer optics that reflect up to about 50% of XUV radiation at normal incidence. This technology has been used to make telescopes for solar imaging (pioneered by the NIXT and MSSTA sounding rockets in the 1990s; current examples are SOHO/EIT and TRACE) and microphotolithography (printing of traces and devices on microchips). microchips as seen in deep ultraviolet light at 17.1 nm by the Extreme ultraviolet Imaging Telescope instrument aboard the SOHO spacecraft]]

Discovery

Soon after infrared radiation had been discovered, the German physicist Johann Wilhelm Ritter began to look for radiation at the opposite end of the spectrum, at the short wavelengths beyond violet. In 1801 he used silver chloride, a light-sensitive chemical, to show that there was a type of invisible light beyond violet, which he called chemical rays. At that time, many scientists, including Ritter, concluded that light was composed of three separate components: an oxidising or calorific component (infrared), an illuminating component (visible light), and a reducing or hydrogenating component (ultraviolet). The unity of the different parts of the spectrum was not understood until about 1842, with the work of Macedonio Melloni, Alexandre-Edmond Becquerel and others. During that time, UV radiation was also called "actinic radiation".

Health concerns and protection

In humans, prolonged exposure to solar UV radiation may result in acute and chronic health effects on the skin, eye, and immune system [http://www.who.int/uv/health/en/]. Tungsten-halogen lamps have bulbs made of quartz, not of ordinary glass. Tungsten-halogen lamps that are not filtered by an additional layer of ordinary glass are a common, useful, and possibly dangerous, source of UVB light. UVC rays are the highest energy, most dangerous type of ultraviolet light. Little attention has been given to UVC rays in the past since they are filtered out by the atmosphere. However, their use in equipment such as pond sterilization units may pose an exposure risk, if the lamp is switched on outside of its enclosed pond sterilization unit. sterilization

Skin

UVA, UVB and UVC all can damage collagen fibers and thereby accelerate aging of the skin. In general, UVA is the least harmful, but can contribute to the aging of skin, DNA damage and possibly skin cancer. It penetrates deeply and does not cause sunburn. Because it does not cause reddening of the skin (erythema) it cannot be measured in the SPF testing. There is no good clinical measurement of the blocking of UVA radiation, but it is important that sunscreen block both UVA and UVB. UVA light is known as "dark-light" and, because of its longer wavelength, can penetrate most windows. It also penetrates deeper into the skin than UVB light and is thought to be a prime cause of wrinkles. UVB light in particular has been linked to skin cancers such as melanoma. The radiation excites DNA molecules in skin cells, causing covalent bonds to form between adjacent thymine bases, producing thymidine dimers. Thymidine dimers do not base pair normally, which can cause distortion of the DNA helix, stalled replication, gaps, and misincorporation. These can lead to mutations, which can result in cancerous growths. The mutagenicity of UV radiation can be easily observed in bacteria cultures. This cancer connection is one reason for concern about ozone depletion and the ozone hole. As a defense against UV radiation, the body tans when exposed to moderate (depending on skin type) levels of radiation by releasing the brown pigment melanin. This helps to block UV penetration and prevent damage to the vulnerable skin tissues deeper down. Suntan lotion that partly blocks UV is widely available (often referred to as "sun block" or "sunscreen"). Most of these products contain an "SPF rating" that describes the amount of protection given. This protection applies only to UVB light. In any case, most dermatologists recommend against prolonged sunbathing.

Eye

High intensities of UVB light are hazardous to the eyes, and exposure can cause welder's flash (photokeratitis or arc eye) and may lead to cataracts, pterygium[http://ajp.amjpathol.org/cgi/content/abstract/162/2/567] [http://ajp.amjpathol.org/cgi/content/abstract/167/2/489], and pinguecula formation. Protective eyewear is beneficial to those who are working with or those who might be exposed to ultraviolet radiation, particularly short wave UV. Given that light may reach the eye from the sides, full coverage eye protection is usually warranted if there is an increased risk of exposure as in high altitude mountaineering. Mountaineers are exposed to higher than ordinary levels of UV radiation, both because there is less atmospheric filtering and because of reflection from snow and ice. Ordinary eyeglasses give some protection, and most plastic lenses give more protection than glass lenses. Some plastic lens materials, such as polycarbonate, block most UV. There are protective treatments available for eyeglass lenses that need it to give better protection. Most intraocular lenses help to protect the retina by absorbing UV radiation.

Immune system

Beneficial effects

A positive effect of UV light is that it induces the production of vitamin D in the skin. Grant (2002) claims tens of thousands of premature deaths occur in the US annually from cancer due to insufficient UVB exposures (apparently via vitamin D deficiency). Another effect of vitamin D deficiency is osteomalacia, which can result in bone pain, difficulty in weight bearing and sometimes fractures. Ultraviolet radiation has other medical applications, in the treatment of skin conditions such as psoriasis. UVB and UVA radiation can be used, in conjunction with psoralens (PUVA treatment).

Uses

UV light has many various uses.

Black lights

PUVA A black light is the name commonly given to a lamp emitting almost entirely long wave UV radiation and very little visible light. Fluorescent black lights are typically made in the same fashion as normal fluorescent lights except that only one phosphor is used instead of the typical 2 or 3 which produce a full spectrum light and the normally clear glass envelope of the bulb is replaced by a deep bluish purple glass called Wood's glass. Wood's glass is a nickel oxide, cobalt oxide-doped glass which blocks virtually all visible light above 400 nanometers. The phosphor typically used for a near 368 to 371 nanometer emission peak is either europium-doped strontium fluoroborate (SrB₄O₇F:Eu²⁺) or europium-doped strontium borate (SrB₄O₇:Eu²⁺) while the phosphor used to produce a peak around 350 to 353 nanometers is lead-doped barium silicate (BaSi₂O₅:Pb⁺). The ultraviolet radiation itself is invisible to the human eye, but illuminating certain materials with UV radiation prompts the visible effects of fluorescence and phosphorescence. Black light testing is commonly used to authenticate antiques and bank notes. It is extensively used in non-destructive testing (NDT); fluorescing fluids are applied to metal structures and illuminated with a black light. Cracks and other artefacts can easily be detected. It is also used to illuminate pictures painted with fluorescent colors (preferably on black velvet to intensify the illusion of self-illumination). The fluorescence it prompts from certain textile fibers is also used as a recreational effect (as seen for instance in the opening credits of the James Bond film A View to a Kill). A View to a Kill In forensic investigations, black lights are used to reveal the presence of trace evidence, such as blood, urine, semen and saliva, by causing visible fluorescence in these substances. The use of this technique by exposé style television news magazines for reporting on the various unsanitary and mysterious stains found in hotel rooms has become such an oft-repeated stunt that it has been lampooned on comedy shows such as The Family Guy.

Fluorescent lamps

Fluorescent lamps produce UV radiation by the emission of low-pressure mercury gas. A phosphorescent coating on the inside of the tubes absorbs the UV and becomes visible. The main mercury emission wavelength is in the UVC range. Unshielded exposure of the skin or eyes to mercury arc lamps that do not have a conversion phosphor is quite dangerous. The light from a mercury lamp is predominantly at discrete wavelengths. Other practical UV sources with more continuous emission spectra include xenon arc lamps (commonly used as sunlight simulators), deuterium arc lamps, mercury-xenon arc lamps, metal-halide arc lamps, and tungsten-halogen incandescent lamps.

Pest control

Ultraviolet fly traps are used for the elimination of various small flying insects. They are attracted to the UV light and are killed using an electrical shock or trapped once they come into contact with the device.

Spectrophotometry

UV/VIS spectroscopy is widely used as a technique in chemistry, for analysis of chemical structure, most notably conjugated systems. UV radiation is often used in visible spectrophotometry to determine the existence of fluorescence a given sample.

Astronomy

spectrophotometry's north pole as seen in ultraviolet light by the Hubble Space Telescope.]] In astronomy, very hot objects preferentially emit UV radiation (see Wien's law). However, the same ozone layer that protects us causes difficulties for astronomers observing from the Earth, so most UV observations are made from space. (see UV astronomy, space observatory)

Analyzing minerals

Ultraviolet lamps are also used in analyzing minerals, gems, and in other detective work including authentication of various collectibles. Materials may look the same under visible light, but fluoresce to different degrees under ultraviolet light; or may fluoresce differently under short wave ultraviolet versus long wave ultraviolet. UV fluorescent dyes are used in many applications (for example, biochemistry and forensics). The fluorescent protein Green Fluorescent Protein (GFP) is often used in genetics as a marker. Many substances, proteins for instance, have significant light absorption bands in the ultraviolet that are of use and interest in biochemistry and related fields. UV-capable spectrophotometers are common in such laboratories.

Photolithography

Ultraviolet radiation is used for very fine resolution photolithography, a procedure where a chemical known as a photoresist is exposed to UV radiation which has passed through a mask. The light allows chemical reactions to take place in the photoresist, and after development (a step that either removes the exposed or unexposed photoresist), a geometric pattern which is determined by the mask remains on the sample. Further steps may then be taken to "etch" away parts of the sample with no photoresist remaining. UV radiation is used extensively in the electronics industry because photolithography is used in the manufacture of semiconductors, integrated circuit components and printed circuit boards.

Checking electrical insulation

printed circuit board and Franklinite containing mineral sample as seen under visible light (top) and fluorescing under UV light (bottom).]] A new application of UV is to detect corona discharge (often simply called "corona") on electrical apparatus. Degradation of insulation of electrical apparatus or pollution causes corona, wherein a strong electric field ionizes the air and excites nitrogen molecules, causing the emission of ultraviolet radiation. The corona degrades the insulation level of the apparatus. Corona produces ozone and to a lesser extent nitrogen oxide which may subsequently react with water in the air to form nitrous acid and nitric acid vapour in the surrounding air. [http://www.seeing-corona.com/]

Sterilization

Ultraviolet lamps are used to sterilize workspaces and tools used in biology laboratories and medical facilities. Commercially-available low pressure mercury-vapor lamps emit about 86% of their light at 254 nanometers (nm) which coincides very well with one of the two peaks of the germicidal effectiveness curve (i.e., effectiveness for UV absorption by DNA). One of these peaks is at about 265 nm and the other is at about 185 nm. Although 185 nm is better absorbed by DNA, the quartz glass used in commercially-available lamps, as well as environmental media such as water, are more opaque to 185 nm than 254 nm (C. von Sonntag et al., 1992). UV light at these germicidal wavelengths causes adjacent thymine molecules on DNA to dimerize, if enough of these defects accumulate on a microorganism's DNA its replication is inhibited, thereby rendering it harmless (even though the organism may not be killed outright). Since microorganisms can be shielded from ultraviolet light in small cracks and other shaded areas, however, these lamps are used only as a supplement to other sterilization techniques.

Disinfecting drinking water

UV radiation can be an effective viricide and bactericide. Disinfection using UV radiation was more commonly used in wastewater treatment applications but is finding increased usage in drinking water treatment. Generally, UV disinfection is more effective for bacteria and virus, which have more exposed genetic material, than for larger pathogens which have outer coatings or that form cyst states (e.g., Giardia) that shield their DNA from the UV light. However, it was recently discovered that ultraviolet radiation can be somewhat effective for treating the microorganism Cryptosporidium. The findings resulted in two [http://www.calgoncarbon.com/company/news/index.cfm?mode=detail&id=DF8B2807-AB22-705E-D9769AEA0B6A744E US patents] and the use of UV radiation as a viable method to treat drinking water.

Food Processing

As consumer demand for fresh and "fresh like" food products increases, the demand for nonthermal methods of food processing is likewise on the rise. In addition, public awareness regarding the dangers of food poisoning is also raising demand for improved food processing methods. Ultraviolet radiation is used in several food processes to remove unwanted microorganisms. UV light can be used to pasteurize fruit juices by pumping the juice over a high intensity ultraviolet light source. The effectiveness of such a process depends on the UV absorbance of the juice (see Beer's law).

Fire detection

Ultraviolet (UV) detectors generally use either a solid-state device, such as one based on silicon carbide or aluminum nitride, or a gas-filled tube as the sensing element. UV detectors which are sensitive to UV light in any part of the spectrum respond to irradiation by sunlight and artificial light. A burning hydrogen flame, for instance, radiates strongly in the 185 to 260 nanometre) range and only very weakly in the IR region, while a coal fire emits very weakly in the UV band yet very strongly at IR wavelengths; thus a fire detector which operates using both UV and IR detectors is more reliable than one with a UV detector alone. Virtually all fires emit some radiation in the UVB band, while the Sun's radiation at this band is absorbed by the Earth's atmosphere. The result is that the UV detector is "solar blind", meaning it will not cause an alarm in response to radiation from the Sun, so it can easily be used both indoors and outdoors. UV detectors are sensitive to most fires, including hydrocarbons, metals, sulfur, hydrogen, hydrazine, and ammonia. Arc welding, electrical arcs, lightning, X-rays used in nondestructive metal testing equipment (though this is highly unlikely), and radioactive materials can produce levels that will activate a UV detection system. The presence of UV-absorbing gases and vapors will attenuate the UV radiation from a fire, adversely affecting the ability of the detector to detect flames. Likewise, the presence of an oil mist in the air or an oil film on the detector window will have the same effect.

Curing of adhesives and coatings

Certain adhesives and coatings are formulated with photoinitiators. When exposed to the correct wavelengths of UV light, polymerisation occurs, and so the adhesives harden or cure. Usually, this reaction is very quick, a matter of a few seconds. Applications include glass and plastic bonding, optical fiber coatings, the coating of flooring, and dental fillings.

External link

- [http://www.iuva.org/ International Ultraviolet Association]

References

- Grant, William B. (2002). [http://www3.interscience.wiley.com/cgi-bin/abstract/91016211/ABSTRACT An estimate of premature cancer mortality in the US due to inadequate doses of solar ultraviolet-B radiation.] Cancer 94 (6), 1867–1875.
- Matsumura Y, Ananthaswamy HN (2004). [http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=pubmed&dopt=Abstract&list_uids=15020192 Toxic effects of UV radiation on the skin.] Toxicol. Appl. Pharmacol. 195 (3), 298-308.
- Hu S, et al. (2004). [http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=pubmed&dopt=Abstract&list_uids=15262692 UV radiation and melanoma in US Hispanics & blacks.] Arch Dermatol. 140 (7), 819-824. Category:Electromagnetic spectrum ms:Ultraungu ja:紫外線 simple:Ultraviolet

Electromagnetic radiation

Electromagnetic radiation is a propagating wave in space with electric and magnetic components. These components oscillate at right angles to each other and to the direction of propagation. The term electromagnetic radiation is also used as a synonym for electromagnetic waves in general, even if they are not radiating or travelling in free space. This sense includes, for example, light travelling through an optical fiber, or electrical energy travelling within a coaxial cable. Electromagnetic (EM) radiation carries energy and momentum which may be imparted when it interacts with matter.

Physics

Theory

Electromagnetic waves of much lower frequency than visible light were predicted by Maxwell's equations and subsequently discovered by Heinrich Hertz. Maxwell derived a wave form of the electric and magnetic equations which made explicit the wave nature of the electric and magnetic fields. These equations displayed the symmetry of the fields. According to the theory, a time-varying electric field generates a magnetic field and vice versa. Thus, an oscillating electric field creates an oscillating magnetic field, which in turn creates an oscillating electric field, and so on. By this means an EM wave is produced which propagates through space.

Properties

Electric and magnetic fields exhibit the property of superposition. This means that the field due to a particular particle or time-varying electric or magnetic field adds to the fields due to other causes. (As magnetic and electric fields are vector fields, this is the vector addition of all the individual electric and magnetic field vectors.) As a result, EM radiation is influenced by various phenomena such as refraction and diffraction. For example, a travelling EM wave incident on a particular arrangement of atoms induces oscillation in the atoms and thus causes them to emit their own EM waves (called wavelets). These emissions interfere with the impinging wave and alter its form. In refraction, a wave moving from one medium to another of a different density changes its speed and direction when it enters the new medium. The ratio of the refractive indices of the media determines the extent of refraction. Refraction is the mechanism by which light disperses into a spectrum when it is shone through a prism. The physics of electromagnetic radiation is electrodynamics, a subfield of electromagnetism. EM radiation exhibits both wave properties and particle properties at the same time (see wave-particle duality). These characteristics are mutually exclusive and appear separately in different circumstances: the wave characteristics appear when EM radation is measured over relatively larger timescales and over larger distances, and the particle characteristics are evident when measuring smaller distances and timescales. EM radiation's behaviours as a wave and as a stream of particles have been confirmed by a large number of experiments.

Wave model

An important aspect of the wave nature of light is frequency. The frequency of a wave is its rate of oscillation and is measured in hertz, the SI unit of frequency, equal to one oscillation per second. Light usually comprises a spectrum of frequencies which sum to form the resultant wave. In addition, frequency affects properties like refraction, in which different frequencies undergo a different level of refraction. A wave has troughs and crests. The wavelength is the distance from crest to crest. Waves in the electromagnetic spectrum vary in size from very long radio waves the size of buildings, to very short gamma-rays smaller than the size of the nucleus of an atom. Frequency has an inverse relationship to the concept of wavelength. When waves travel from one medium to another, their frequency remains exactly the same - only their wavelength and/or speed changes. Waves can also be described by their radiant energy. Interference is the superposition of two or more waves resulting in a new wave pattern. The way that these coincide causes different types of interference.

Particle model

In the particle model of EM radiation, EM radiation is quantized as particles called photons. Quantisation of light represents the discrete packets of energy which constitute the radiation. The frequency of the radiation determines the magnitude of the energy of the particles. Moreover, these particles are emitted and absorbed by charged particles, so photons act as transporters of energy. A photon absorbed by an atom excites an electron and elevates it to a higher energy level. If the energy is great enough, the electron is liberated from the atom in a process called ionization. Conversely, an electron which descends to a lower energy level in an atom emits a photon of light equal to the energy difference. The energy levels of electrons in atoms are discrete. Therefore, each element has its own characteristic frequencies. Together these effects explain the absorption spectra of light. The dark bands in the spectrum are due to the atoms in the intervening medium which absorb different frequencies of the light. The composition of the medium through which the light travels determines the nature of the absorption spectrum. For instance, in a distant star, dark bands in the light it emits are due to the atoms in the atmosphere of the star. These bands correspond to the allowed energy levels in the atoms. A similar phenomenon occurs for emission. As the electrons descend to lower energy levels, a spectrum which represents the jumps between the energy levels of the electrons is exhibited. This is manifested in the emission spectrum of nebulae.

Speed of propagation

Any electric charge which accelerates, or any changing magnetic field, produces electromagnetic radiation. Electromagnetic information about the charge travels at the speed of light. Accurate treatment thus incorporates a concept known as retarded time (as opposed to advanced time, which is unphysical in light of causality), which adds to the expressions for the electrodynamic electric field and magnetic field. These extra terms are responsible for electromagnetic radiation. When any wire (or other conducting object such as an antenna) conducts alternating current, electromagnetic radiation is propagated at the same frequency as the electric current. Depending on the circumstances, it may behave as a wave or as particles. As a wave, it is characterized by a velocity (the speed of light), wavelength, and frequency. When considered as particles, they are known as photons, and each has an energy related to the frequency of the wave given by Planck's relation E = hν, where E is the energy of the photon, h = 6.626 × 10^-34 J·s is Planck's constant, and ν is the frequency of the wave. One rule is always obeyed regardless of the circumstances. EM radiation in a vacuum always travels at the speed of light, relative to the observer, regardless of the observer's velocity. (This observation led to Albert Einstein's development of the theory of special relativity.)

Electromagnetic spectrum

Generally, EM radiation is classified by wavelength into electrical energy, radio, microwave, infrared, the visible region we perceive as light, ultraviolet, X-rays and gamma rays. The behavior of EM radiation depends on its wavelength. Higher frequencies have shorter wavelengths, and lower frequencies have longer wavelengths. When EM radiation interacts with single atoms and molecules, its behavior depends on the amount of energy per quantum it carries. Spectroscopy can detect a much wider region of the EM spectrum than the visible range of 400 nm to 700 nm. A common laboratory spectroscope can detect wavelengths from 2 nm to 2500 nm. More in-depth information about the physical properties of objects, gases, or even stars can be obtained from this type of device. It is widely used in astrophysics. For example, many hydrogen atoms emit radio waves which have a wavelength of 21.12 cm.

Light

EM radiation with a wavelength between 400 nm and 700 nm is detected by the human eye and perceived as visible light. If radiation having a frequency in the visible region of the EM spectrum shines on an object, say, a bowl of fruit, this results in our visual perception of identifying information from the scene. Our brain's visual system processes the multitude of reflected frequencies into different shades and hues, and through this not-entirely-understood "psychophysical phenomenon," most humans perceive a bowl of fruit. In the vast majority of cases, however, the information carried by light is not directly apprehensible by human senses. Natural sources produce EM radiation across the spectrum; so, too, can human technology manipulate a broad range of wavelengths. Optical fiber transmits light which, although not suitable for direct viewing, can carry data. Those data can be translated into sound or an image. The coded form of such data is similar to that used with radio waves.

Radio waves

Radio waves carry information by varying amplitude and by varying frequency within a frequency band. When EM radiation impinges upon a conductor, it couples to the conductor, travels along it, and induces an electric current on the surface of that conductor by exciting the electrons of the conducting material. This effect (the skin effect) is used in antennas. EM radiation may also cause certain molecules to absorb energy and thus to heat up; this is exploited in microwave ovens.

Derivation

Electromagnetic waves as a general phenomenon were predicted by the classical laws of electricity and magnetism, known as Maxwell's equations. If you inspect Maxwell's equations without sources (charges or currents) then you will find that, along with the possibility of nothing happening, the theory will also admit nontrivial solutions of changing electric and magnetic fields. (For symbol definitions see magnetic field.) :

\nabla \cdot \mathbf = 0

\nabla \times \mathbf = -\frac \mathbf

\nabla \cdot \mathbf = 0

\nabla \times \mathbf = \mu_0 \epsilon_0 \frac \mathbf

\mathbf=\mathbf=\mathbf

is a solution, but there might be other solutions as well. Let us employ a useful identity from vector calculus. :

\nabla \times \left( \nabla \times \mathbf \right) = \nabla \left( \nabla \cdot \mathbf \right) - \nabla^2 \mathbf

Where

\mathbf

can be any vector function. Taking the curl of the curl equations and applying the identity, we get the following. :

\nabla^2 \mathbf = \mu_0 \epsilon_0 \frac \mathbf

\nabla^2 \mathbf = \mu_0 \epsilon_0 \frac \mathbf

These types of equations are identified as linear wave equations with wave speed

\frac

. Amazingly, this speed happens to be exactly the speed of light! Maxwell's equations have unified the permittivity of free space

\epsilon_0

, the permeability of free space

\mu_0

, and the speed of light itself:

c = \frac

. Before this derivation it was not known that there was such a strong relationship between light and electricity and magnetism. But these are only two equations and we started with four, so there is still more information pertaining to these waves hidden within Maxwell's equations. Let's consider a generic vector wave for the electric field. :

\mathbf = \mathbf_0 f\left( \hat \cdot \mathbf - c t \right)

Here

\mathbf_0

is the constant amplitude,

f

is any second differentiable function,

\hat

is a unit vector in the direction of propagation, and

\hat

is a position vector. We observe that

f\left( \hat \cdot \mathbf - c t \right)

is a generic solution to the wave equation. In other words :

\nabla^2 f\left( \hat \cdot \mathbf - c t \right) = \frac \frac f\left( \hat \cdot \mathbf - c t \right)

, for a generic wave traveling in the

\hat

direction. The proof of this is trivial. This form will satisfy the wave equation, but will it satisfy all of Maxwell's equations, and with what corresponding magnetic field? :

\nabla \cdot \mathbf = \hat \cdot \mathbf_0 f'\left( \hat \cdot \mathbf - c t \right) = 0

\mathbf \cdot \hat = 0

The first of Maxell's equations implies that electric field is orthogonal to the direction the wave propagates. :

\nabla \times \mathbf = \hat \times \mathbf_0 f'\left( \hat \cdot \mathbf - c t \right) = -\frac \mathbf

\mathbf = \frac \hat \times \mathbf

The second of Maxwell's equations yields the magnetic field. The remaining equations will be satisfied by this choice of

\mathbf,\mathbf

. Not only are the electric and magnetic field waves traveling at the speed of light, but they have a special restricted orientation and proportional magnitudes,

\mathbf_0 = c \mathbf_0

. The electric field, magnetic field, and direction of wave propagation are all orthogonal and the wave propagates in the same direction as

\mathbf \times \mathbf

. Visualizing yourself as an electromagnetic wave traveling forward, the electric field might be oscillating up and down, while the magnetic field oscillates right and left; but you can rotate this picture around with the electric field oscillating right and left and the magnetic field oscillating down and up. This is a different solution that is traveling in the same direction. This arbitrariness in the orientation, with respect to propagation direction, is known as polarization.

References

-
-
-

External links

; General
- [http://www.sengpielaudio.com/calculator-wavelength.htm Conversion of frequency to wavelength and back - electromagnetic, radio and sound waves]
- [http://www.scienceofspectroscopy.info The Science of Spectroscopy - a learning tool for spectroscopy] ; Patents
- Greenleaf Whittier Pickard - - Intelligence intercommunication by magnetic wave component ko:전자기파 ja:電磁波

X-ray

] ] An X-ray or Röntgen ray is a form of electromagnetic radiation with a wavelength in the range of 10 nanometers to 100 picometers (corresponding to frequencies in the range 30 PHz to 3 EHz). X-rays are primarily used for diagnostic medical imaging and crystallography. X-rays are a form of ionizing radiation and as such can be dangerous.

Physics

X-rays with a wavelength approximately longer than 0.1 nm are called soft X-rays. At wavelengths shorter than this, they are called hard X-rays. Hard X-rays overlap the range of "long"-wavelength (lower energy) gamma rays, however the distinction between the two terms depends on the source of the radiation, not its wavelength: X-ray photons are generated by energetic electron processes, gamma rays by transitions within atomic nuclei. The basic production of X-rays is by accelerating electrons in order to collide with a metal target (tungsten usually). Here the electrons suddenly decelerate upon colliding with the metal target and if enough energy is contained within the electron it is able to knock out an electron from the inner shell of the metal atom and as a result electrons from higher energy levels then fill up the vacancy and X-ray photons are emitted. This causes the spectral line part of the wavelength distribution. There is also a continuum bremsstrahlung component given off by the electrons as they are scattered by the strong electric field near the high Z (proton number) nuclei. Nowadays, for many applications, X-ray production is achieved by synchrotrons (see synchrotron light).

Detectors

Photographic plates

The detection of X-rays is based on various methods. The most commonly known method are a photographic plate and a fluorescent screen. The X-ray photographic plate is frequently used in hospitals to produce images of the internal organs and bones of a patient. The part of the patient to be X-rayed is placed between the X-ray source and the photographic plate to produce what is a shadow of all the internal structure of that particular part of the body being X-rayed. The X-rays are blocked by dense tissues such as bone and pass through soft tissues. Where the X-rays strike the photographic plate it turns black when it is developed. So where the X-rays go through "soft" parts of the body like organs and skin the plate turns black. Contrast compounds containing barium or iodine can be injected in the artery of a particular organ. The contrast compounds strongly block the X-rays and hence the circulation of the organ can be more readily seen. Another method of detecting X-rays is a fluorescent plate. In modern hospitals a special plastic sheet is used in place of the photographic plate. The plastic sheet is read by a scanning laser beam. The resultant image is then stored in a computer. The plastic sheet can be used over and over again.

Geiger counters

Initially, most common detection methods were based on the ionisation of gases, as in the Geiger-Müller counter: a sealed cylinder with a polymer window contains a gas, and a wire, and a high voltage is applied between the cylinder (cathode) and the wire (anode). When an X-ray photon enters the cylinder, it ionizes the gas which becomes conducting, creating a current flow (a kind of flash); this peak of current is detected and is called a "count". When the high voltage between anode and cathode is decreased, the detector is no longer saturated, and the height of the current peak is proportional to the energy of the photon; it is thus called a "proportional counter". Most of time, the cylinder is not sealed but is constantly fed with "fresh gas", is thus called a "flow counter". This proportionality property allows filtering the "interesting" peaks from the noise and other photons, but the resolution in energy is not enough to determine the energy spectrum; such a feature requires a diffracting crystal to first separate the different photons, the method is called wavelength dispersive X-ray spectroscopy (WDX or WDS).

Scintillators

Some materials such as NaI can "convert" an X photon to a visible photon; an electronic detector can be built by adding a photomultiplier. These detectors are called "scintillators", filmscreens or "scintillation counters". The main advantage of using these is that an adequate image can be obtained while subjecting the patient to a much lower dose of X-rays.

Direct semiconductor detectors

Since the 1970s, new semiconductor detectors have been developed (silicon or germanium doped with lithium, Si(Li) or Ge(Li)). X-ray photons are converted to electron-hole pairs in the semiconductor and are collected to detect the X-rays. When the temperature is low enough (the detector is cooled by Peltier effect or best by liquid nitrogen), it is possible to directly determine the X-ray energy spectrum; this method is called energy dispersive X-ray spectroscopy (EDX or EDS); it is often used in small X-ray fluorescence spectrometers. These detectors are sometimes called "solid detectors". Cadmium telluride (CdTe) and its alloy with zinc, cadmium zinc telluride detectors have have an increased sensitivity, which allows lower doses of X-rays to be used. Silicon drift detectors (SDDs), produced by conventional semiconductor fabrication, now provide a cost-effective and high resolving radiation measurement. They replace conventional X-ray detectors, such as Si(Li)s, as they do not need to be cooled with liquid nitrogen.

Scintillator + Semiconductor detectors

With the advent of large semiconductor array detectors it has become possible to design detector systems using a scintillator screen to convert from X-rays to visible light which is then converted to electrical signals in an array detector.

Visibility to the Human Eye

It is commonly thought that X-rays are invisible to the human eye, and for almost all everyday uses of X-rays this may seem true; however, very strictly speaking, it is actually false. In special circumstances, X-rays are in fact visible to the "naked eye". An effect first discovered by Brandes in experimentation a short time after Röntgen's landmark 1895 paper; he reported, after dark adaptation and placing his eye close to an X-ray tube, seeing a faint "blue-gray" glow which seemed to originate within the eye itself.[http://www.orau.org/ptp/articlesstories/invisiblelight.htm] Upon hearing this, Röntgen reviewed his record books and found he in fact, also saw the effect. When placing an X-ray tube on the opposite side of a wooden door Röntgen saw the same blue glow seeming to emanate from the eye itself, but thought his observations were spurious due to the fact that he only saw the effect when he used one type of tube. Later he realized that the tube which created the effect was the only one which produced X-rays powerful enough to make the glow plainly visible and the experiment was thereafter repeated readily. The fact that X-rays are actually faintly visible to the dark-adapted naked eye has largely been forgotten today is probably due to the lack of desire to repeat what we would now see as a recklessly dangerous and harmful experiment with ionizing radiation. It is not known what the exact mechanism in the eye is which produces the visibility and it could be due to either conventional detection (excitation of rhodopsin molecules in the retina), direct excitation of retinal nerve cells, or secondary detection via, for instance, X-ray induction of phosphorescence in the eyeball and then conventional retinal detection of the secondarily produced visible light.

Medical uses

phosphorescence phosphorescence Since Röntgen's discovery that X-rays can identify bony structures, X-rays have been developed for their use in medical imaging. Radiology is a specialized field of medicine that employs radiography and other techniques for diagnostic imaging. Indeed, this is probably the most common use of X-ray technology. The use of X-rays are especially useful in the detection of pathology of the skeletal system, but are also useful for detecting some disease processes in soft tissue. Some notable examples are the very common chest X-ray, which can be used to identify lung diseases such as pneumonia, lung cancer or pulmonary edema, and the abdominal X-ray, which can detect ileus (blockage of the intestine), free air (from visceral perforations) and free fluid (in ascites). In some cases, the use of X-rays is debatable, such as gallstones (which are rarely radiopaque) or kidney stones (which are often visible, but not always). Also, Traditional plain X-rays pose very little use in the imaging of soft tissues such as the brain or muscle. Imaging alternatives for soft tissues are computed axial tomography (CAT or CT scanning), magnetic resonance imaging (MRI) or ultrasound. X-rays are also used in "real-time" procedures such as angiography or contrast studies of the hollow organs (e.g. barium enema of the small or large intestine) using fluoroscopy. Angioplasty, medical interventions of the arterial system, rely heavily on X-ray-sensitive contrast to identify potentially treatable lesions. Radiotherapy, a curative medical intervention, now used almost exclusively for cancer, employs higher energies of radiation.

History

Among the important early researchers in X-rays were Professor Ivan Pului, Sir William Crookes, Johann Wilhelm Hittorf, Eugen Goldstein, Heinrich Hertz, Philipp Lenard, Hermann von Helmholtz, Nikola Tesla, Thomas Edison, Charles Glover Barkla, Max von Laue, and Wilhelm Conrad Röntgen. Wilhelm Conrad Röntgen Physicist Johann Hittorf (1824 - 1914) observed tubes with energy rays extending from a negative electrode. These rays produced a fluorescence when they hit the glass walls of the tubes. In 1876 the effect was named "cathode rays" by Eugen Goldstein. Later, English physicist William Crookes investigated the effects of energy discharges on rare gases, and constructed what is called the Crookes tube. It is a glass vacuum cylinder, containing electrodes for discharges of a high voltage electric current. He found, when he placed unexposed photographic plates near the tube, that some of them were flawed by shadows, though he did not investigate this effect.

Tesla

In April 1887, Nikola Tesla began to investigate X-rays using high voltages and vacuum tubes of his own design, as well as Crookes tubes. From his technical publications, it is indicated that he invented and developed a special single-electrode X-ray tube, which differed from other X-ray tubes in having no target electrode. He stated these facts in his 1897 X-ray lecture before the New York Academy of Sciences. The principle behind Tesla's device is nowadays called the Bremsstrahlung process, in which a high-energy secondary X-ray emission is produced when charged particles (such as electrons) pass through matter. By 1892, Tesla performed several such experiments, but he did not categorize the emissions as what were later called X-rays, instead generalizing the phenomenon as radiant energy. He did not publicly declare his findings nor did he make them widely known. His subsequent X-ray experimentation by vacuum high field emissions led him to alert the scientific community to the biological hazards associated with X-ray exposure.

Hertz

In 1892, Heinrich Hertz began experimenting and demonstrated that cathode rays could penetrate very thin metal foil (such as aluminium). Philipp Lenard, a student of Heinrich Hertz, further researched this effect. He developed a version of the cathode tube and studied the penetration by X-rays of various materials. Philipp Lenard, though, did not realize that he was producing X-rays. Hermann von Helmholtz formulated mathematical equations for X-rays. He postulated a dispersion theory before Röntgen made his discovery and announcement. It was formed on the basis of the electromagnetic theory of light (Wiedmann's Annalen, Vol. XLVIII). However, he did not work with actual X-rays.

Röntgen

Hermann von Helmholtz] On November 8 1895, Wilhelm Conrad Röntgen, a German scientist, began observing and further documenting X-rays while experimenting with vacuum tubes. Röntgen, on December 28, 1895, wrote a preliminary report "On a new kind of ray: A preliminary communication". He submitted it to the Würzburg's Physical-Medical Society journal. This was the first formal and public recognition of the categorization of X-rays. Röntgen referred to the radiation as "X", to indicate that it was an unknown type of radiation. The name stuck, although (over Röntgen's great objections), many of his colleagues suggested calling them Röntgen rays. They are still referred to as such in many languages, where available see the list of titles for versions of this article in other languages. Röntgen received the first Nobel Prize in Physics for his discovery. Röntgen was working on a primitive cathode ray generator that was projected through a glass vacuum tube. All of a sudden he noticed a faint green light against the wall. The odd thing he had noticed, was that the light from the cathode ray generator was traveling through a bunch of the materials in its way (paper,wood, and books). He then started to put various objects in front of the generator,and as he was doing this, he noticed that the outline of the bones from his hand were displayed on the wall. He then studied this phenomenon in seclusion.

Edison

In 1895, Thomas Edison investigated materials' ability to fluoresce when exposed to X-rays, and found that calcium tungstate was the most effective substance. Around March 1896, the fluoroscope he developed became the standard for medical X-ray examinations. Nevertheless, Edison dropped X-ray research around 1903 after the death of Clarence Madison Dally, one of his glassblowers. Dally had a habit of testing X-ray tubes on his hands, and acquired a cancer in them so tenacious that both arms were amputated in a futile attempt to save his life[http://www.ratical.org/radiation/KillingOurOwn/KOO6.html].

The 20th century and beyond

In 1906, physicist Charles Barkla discovered that X-rays could be scattered by gases, and that each element had a characteristic X-ray. He won the 1917 Nobel Prize in Physics for this discovery. The use of X-rays for medical purposes (to develop into the field of radiation therapy) was pioneered by Major John Hall-Edwards in Birmingham, England. In 1908, he had to have his left arm amputated owing to the spread of X-ray dermatitis[http://www.birmingham.gov.uk/xray]. In the 1950s X-rays were first harnessed to produce an X-ray microscope. X-ray microscope of, and occultation of the X-ray background by, the Moon.]] In the 1980s an X-ray laser device was proposed as part of the Reagan administration's Strategic Defense Initiative, but the first and only test of the device (a sort of laser "blaster", or death ray, powered by a thermonuclear explosion) gave inconclusive results. For technical and political reasons, the overall project (including the X-ray laser) was de-funded (though was later revived by the second Bush administration as National Missile Defense using different technologies). In the 1990s the Chandra X-Ray Observatory was launched, allowing the exploration of the very violent processes in the universe which produce X-Rays. Unlike visible light, which is a relatively stable view of the universe, the X-ray universe is unstable, it features stars being torn apart by black holes, galactic collisions, and novas, neutron stars that build up layers of plasma that then explode into space.

References

- [http://imagers.gsfc.nasa.gov/ems/xrays.html Nasa] Goddard Space Flight centre introduction to x-rays.
- Way Out There in the Blue: Reagan, Star Wars and the End of the Cold War, Frances Fitzgerald, Simon & Schuster (2001). ISBN 0743200233

Nanometre

To help compare different orders of magnitudes this page lists lengths between 10^-9 m (metre) and 10^-8 m (1 nm and 10 nm).
- Lengths shorter than 1 nm
- 1 nm = 1 nanometre = 1000 picometres = 10 Ångströms
- is roughly the length of a sucrose molecule, calculated by Albert Einstein.
- 1.1 nm — diameter of a single-walled carbon nanotube
- 2 nm — diameter of DNA helix
- 3 nm — flying height of the head of a hard disk
- Lengths longer than 10 nm

1 E-7 m

To help compare different orders of magnitude this page lists lengths between 10^-7 and 10^-6 m (100 nm and 1 µm).
- Distances shorter than 100 nm
- 100 nm — greatest particle size that can fit through a surgical mask
- 120 nm — greatest particle size that can fit through a ULPA filter [http://www.ristenbatt.com/filt_eff.htm]
- 125 nm — standard depth of pits on compact discs (width: 500 nm, length: 850 nm to 3.5 µm)
- 180 nm — typical length of the rabies virus
- 200 nm — typical size of a Mycoplasma bacterium, among the smallest bacteria
- 280 nm — near ultraviolet wavelength
- 300 nm — greatest particle size that can fit through a HEPA filter
- 380-420 nm — wavelength of violet light (see color and optical spectrum)
- 420-440 nm — wavelength of indigo light
- 440-500 nm — wavelength of blue light
- 500-520 nm — wavelength of cyan light
- 520-565 nm — wavelength of green light
- 565-590 nm — wavelength of yellow light
- 590-625 nm — wavelength of orange light
- 625-740 nm — wavelength of red light
- Distances longer than 1 µm

Photolithography

Photolithography is a process used in semiconductor device fabrication to transfer a pattern from a photomask (also called reticle) to the surface of a substrate. Often crystalline silicon in the form of a wafer is used as a choice of substrate, although there are several other options including, but not limited to, glass, sapphire, and metal. Photolithography (also referred to as "microlithography" or "nanolithography") bears a similarity to the conventional lithography used in printing and shares some of the fundamental principles of photographic processes. Photolithography involves a combination of:
- substrate preparation
- photoresist application
- soft-baking
- exposure
- developing
- hard-baking
- etching and various other chemical treatments (thinning agents, edge-bead removal etc.) in repeated steps on an initially flat substrate. A part of a typical silicon lithography procedure would begin by depositing a layer of conductive metal several nanometers thick on the substrate. A layer of photoresist -- a chemical that hardens when exposed to light (often ultraviolet) -- is applied on top of the metal layer. The photoresist is selectively "hardened" by illuminating it in specific places. For this purpose a transparent plate with patterns printed on it, called a photomask or shadowmask, is used together with an illumination source to shine light on specific parts of the photoresist. Some photoresists work well under broadband ultraviolet light, whereas others are designed to be sensitive at specific frequencies to ultraviolet light, it is also possible to use other types of resist that are sensitive to X-Rays and others that are sensitive to electron-beam exposure. Generally most types of photoresist will be available as either "positive" or "negative". With positive resists the area that you can see (masked) on the photomask is the area that you will see upon developing of the photoresist. With negative resists it is the inverse, so any area that is exposed will remain, whilst any areas that is not exposed will be developed. After developing, the resist is usually hard-baked before subjecting to a chemical etching stage which will remove the metal underneath. Finally, the hardened photoresist is etched using a different chemical treatment, and all that remains is a layer of metal in the same shape as the mask (or the inverse if negative resist has been used). Lithography is used because it affords exact control over the shape and size of the objects it creates, and because it can create patterns over an entire surface simultaneously. Its main disadvantages are that it requires a substrate to start with, it is not very effective at creating shapes that are not flat, and it can require extremely clean operating conditions. In a complex integrated circuit, (for example, CMOS) a wafer will go through the photolithographic area up to 50 times. For Thin-Film-Transistor (TFT) processing many fewer photolithographical processes are usually required.

Technology

A wafer is introduced onto an automated "wafertrack" system. This track consists of handling robots, bake/cool plates, and coat/develop units. The robots are used to transfer wafers from one module to another. The wafer is initially heated to a temperature sufficient to drive off any moisture that may be present on the wafer surface. Hexa-methyl-disilizane (HMDS) is applied in either liquid or vapor form in order to promote better adhesion of the photosensitive polymeric material, called photoresist. Photoresist is dispensed in a liquid form onto the wafer as it undergoes rotation. The speed and acceleration of this rotation are important parameters in determining the resulting thickness of the applied photoresist. The photoresist-coated wafer is then transferred to a hot plate, where a "soft bake" is applied to drive off excess solvent before the wafer is introduced into the exposure system. The desired pattern is then projected onto the wafer in either a machine called a stepper or scanner. The stepper/scanner functions similarly to a slide projector. Light from a mercury arc lamp or excimer laser is focused through a complex system of lenses onto a "mask" (also called a reticle), containing the desired image. The light passes through the mask and is then focused to produce the desired image on the wafer through a reduction lens system. The reduction of the system can vary depending on design, but is typically on the order of 4X-5X in magnitude. When the image is projected onto the wafer, the photoresist material undergoes some wavelength-specific radiation-sensitive chemical reactions, which cause the regions exposed to light to be either more or less acidic. If the exposed regions become more acidic, the material is called a positive photoresist, while if it becomes less susceptible it is a negative photoresist. The resist is then "developed" by exposing it to an alkaline solution that removes either the exposed (positive photoresist) or the unexposed (negative photoresist). This process takes place after the wafer is transferred from the exposure system back to the wafertrack. Developers originally often contained sodium hydroxide (NaOH). However, sodium is considered an extremely undesirable contaminant in MOSFET fabrication because it degrades the insulating properties of gate oxides. Metal-ion-free developers such as tetramethyl ammonium hydroxide (TMAH) are now used. A post-exposure bake is performed before developing, typically to help reduce standing wave phenomena caused by the destructive and constructive interference patterns of the incident light. The develop chemistry is delivered in a similar fashion to how the photoresist was applied. The resulting wafer is then "hardbaked" on a bake plate at high temperature in order to solidify the remaining photoresist, to better serve as a protecting layer in future ion implantation, wet chemical etching, or plasma etching. The ability to project a clear image of a very small feature onto the wafer is limited by the wavelength of the light that is used and the ability of the reduction lens system to capture enough diffraction orders from the illuminated mask. Current state-of-the-art photolithography tools use deep ultraviolet (DUV) light with wavelengths of 248 and 193 nm, which allow minimum resist feature sizes down to 65nm. Optical lithography can be extended to feature sizes below 65nm using 193nm and liquid immersion techniques. Also termed immersion lithography, this enables the use of optics with numerical apertures exceeding 1.0. The liquid used is typically ultra-pure, deionised water, which provides for a refractive index above that of the usual air gap between the lens and the wafer surface. This is continually circulated to eliminate thermally-induced distortions. Using water will only allow NA's of up to ~1.4 but higher refractive index materials will allow the effective NA to be increased. Tools using 157nm wavelength DUV in a manner similar to current exposure systems have been developed. These were once targeted to succeed 193nm at the 65nm feature size node but have now all but been eliminated by the introduction of immersion lithography. This was due to persistent technical problems with the 157nm technology and economic considerations that provided strong incentives for the continued use of 193nm technology. Beyond the 45nm node Extreme ultraviolet lithography may be required. EUV lithography systems are currently under development which will use 13.5nm wavelengths, approaching the regime of x-rays. The image for the mask is originated from a computerized data file. This data file is converted to a series of polygons and written onto a square fused quartz substrate covered with a layer of chrome using a photolithographic process. A beam of electrons is used to expose the pattern defined in the data file and travels over the surface of the substrate in either a vector or raster scan manner. Where the photoresist on the mask is exposed, the chrome can be etched away, leaving a clear path for the light in the stepper/scanner systems to travel through. Work is in progress on an optical maskless lithography tool. This uses a digital micro-mirror array to directly manipulate reflected light without the need for an intervening mask. Throughput is inherently low, but the elimination of mask-related production costs - which are rising exponentially with every technology generation - means that such a system would be far more cost-effective for small-scale manufacturing applications.

Latin

Latin is an ancient Indo-European language originally spoken in the region around Rome called Latium. It gained great importance as the formal language of the Roman Empire. All Romance languages, those being most notably Spanish, French, Portuguese, Italian, and Romanian, are descended from Latin, and many words based on Latin are found in other modern languages such as English. The Latin alphabet, derived from the Greek, remains the most widely-used alphabet in the world. It is said that 80 percent of scholarly English words are derived from Latin (in a large number of cases by way of French). Moreover, in the Western world, Latin was a lingua franca, the learned language for scientific and political affairs, for more than a thousand years, being eventually replaced by French in the 18th century and English in the late 19th. Ecclesiastical Latin remains the formal language of the Roman Catholic Church to this day, and thus the official national language of the Vatican. The Church used Latin as its primary liturgical language until the Second Vatican Council in the 1960s. Latin is also still used (drawing heavily on Greek roots) to furnish the names used in the scientific classification of living things. The modern study of Latin, along with Greek, is known as Classics.

Main features

Latin is a synthetic inflectional language: affixes (which usually encode more than one grammatical category) are attached to fixed stems to express gender, number, and case in adjectives, nouns, and pronouns, which is called declension; and person, number, tense, voice, mood, and aspect in verbs, which is called conjugation. There are five declensions (declinationes) of nouns and four conjugations of verbs. There are six noun cases: #nominative (used as the subject of the verb or the predicate nominative), #genitive (used to indicate relation or possession, often represented by the English of or the addition of s to a noun), #dative (used of the indirect object of the verb, often represented by the English to or for), #accusative (used of the direct object of the verb, or object of the preposition in some cases), #ablative (separation, source, cause, or instrument, often represented by the English by, with, from), #vocative (used of the person or thing being addressed). In addition, some nouns have a locative case used to express location (otherwise expressed by the ablative with a preposition such as in), but this survival from Proto-Indo-European is found only in the names of lakes, cities, towns, small islands, and a few other words related to locations, such as "house", "ground", and "countryside". Latin itself, being a very old language, is far closer to Proto-Indo-European than are most modern Western European languages; it has, in fact, about the same relationship with PIE as modern Italian or French has to Latin. There are six general tenses in Latin (technically they are tense/aspect/mood complexes). The indicative mood can be used with all of them. The subjunctive mood, however, has only present, imperfect, perfect, and pluperfect tenses. These tenses in the subjunctive mood do not completely correlate in meaning to the tenses in the indicative. The following examples are of the first conjugation verb "laudare" ("to praise") in the indicative mood and the active voice:
Primary sequence tenses
# present (laudo, "I praise") # imperfect (laudabam, "I was praising") # future (laudabo, "I shall praise," "I will praise")
Secondary sequence tenses
# perfect (laudavi, "I praised", "I have praised") # pluperfect (laudaveram, "I had praised") # future perfect (laudavero, "I shall have praised," "I will have praised") The future perfect tense can also imply a normal future idea (like in "When I will have run...") and so may also sometimes be included in the primary sequence.
Latin and Romance
After the collapse of the Roman Empire, Latin evolved into the various Romance languages. These were for many centuries only spoken languages, Latin still being used for writing. For example, Latin was the official language of Portugal until 1296 when it was replaced by Portuguese. The Romance languages evolved from Vulgar Latin, the spoken language of common usage, which in turn evolved from an older speech which also produced the formal classical standard. Latin and Romance differ (for example) in that Romance had distinctive stress, whereas Latin had distinctive length of vowels. In Italian and Sardo logudorese, there is distinctive length of consonants and stress, in Spanish only distinctive stress, and in French even stress is no longer distinctive. Another major distinction between Romance and Latin is that all Romance languages, excluding Romanian, have lost their case endings in most words except for some pronouns. Romanian retains a direct case (nominative/accusative), an indirect case (dative/genitive), and vocative. In Italy, Latin is still compulsory in secondary schools as Liceo Classico and Liceo Scientifico which are usually attended by people who aim to the highest level of education. In Liceo Classico Ancient Greek is a compulsory subject.
Latin and English
See Latin influence in English for a more complete exposition. English grammar is independent of Latin grammar, though prescriptive grammarians in English have been heavily influenced by Latin. Attempts to make English grammar follow Latin rules — such as the prohibition against the split infinitive — have not worked successfully in regular usage. However, as many as half the words in English were derived from Latin, including many words of Greek origin first adopted by the Romans, not to mention the thousands of French, hundreds of Spanish, Portuguese and Italian words of Latin origin that have also enriched English. During the 16th and on through the 18th century English writers created huge numbers of new words from Latin and Greek roots. These words were dubbed "inkhorn" or "inkpot" words (as if they had spilled from a pot of ink). Many of these words were used once by the author and then forgotten, but some remain. Imbibe, extrapolate, dormant and inebriation are all inkhorn terms carved from Latin words. In fact, the word etymology is derived from the Greek word etymologia, meaning "true sense of the word." Latin was once taught in many of the schools in Britain with academic leanings - perhaps 25% of the total [http://www.channel4.com/history/microsites/T/teachem2/thennow/]. However, the requirement for it was gradually abandoned in the professions such as the law and medicine, and then, from around the late 1960s, for admission to university. After the introduction of the Modern Language GCSE in the 1980s, it was gradually replaced by other languages, although it is now being taught by more schools along with other classical languages.
Latin education
The linguistic element of Latin courses offered in high schools or secondary schools, and in universities, is primarily geared toward an ability to translate Latin texts into modern languages, rather than using it in oral communication. As such, the skill of reading is heavily emphasized, whereas speaking and listening skills are barely touched upon. However, there is a growing movement, sometimes known as the Living Latin movement, whose supporters believe that Latin can, or should, be taught in the same way that modern "living" languages are taught, that is, as a means of both spoken and written communication. One of the most interesting aspects of such an approach is that it assists speculative insight into how many of the ancient authors spoke and incorporated sounds of the language stylistically; without understanding how the language is meant to be heard it is very difficult to identify patterns in Latin poetry. Institutions offering Living Latin instruction include the Vatican and the University of Kentucky. In Britain the Classical Association encourages this approach, and there has been something of a vogue for books describing the adventures of a mouse called Minimus. In the United States there is a thriving competitive organization for high school Latin students, the National Junior Classical League (the second-largest youth organization in the world after the Boy Scouts), backed up by the Senior Classical League for college students. Many would-be international auxiliary languages have been heavily influenced by Latin, and the moderately successful Interlingua considers itself to be the modernized and simplified version of the language (le latino moderne international e simplificate). Latin translations of modern literature such as Paddington Bear, Winnie the Pooh, Harry Potter and the Philosopher's Stone, Le Petit Prince, Max und Moritz, and The Cat in the Hat have also helped boost interest in the language.
See also

About the Latin language

- Latin grammar
- Latin spelling and pronunciation
- Latin declension
- Latin conjugation
- Latin alphabet
- List of Latin words with English derivatives
- Latin verbs with English derivatives
- Latin nouns with English derivatives
- ablative absolute
- Word order in Latin
About the Latin literary heritage

- Latin literature
- Romance languages
- Loeb Classical Library
- List of Latin phrases
- List of Latin proverbs
- Brocard
- List of Latin and Greek words commonly used in systematic names
- List of Latin place names in Europe
- Carmen Possum
Other related topics

- Roman Empire
- Internationalism
References

- Bennett, Charles E. Latin Grammar (Allyn and Bacon, Chicago, 1908)
- N. Vincent: "Latin", in The Romance Languages, M. Harris and N. Vincent, eds., (Oxford Univ. Press. 1990), ISBN 0195208293
- Waquet, Françoise, Latin, or the Empire of a Sign: From the Sixteenth to the Twentieth Centuries (Verso, 2003) ISBN 1859844022; translated from the French by John Howe.
- Wheelock, Frederic. Latin: An Introduction (Collins, 6th ed., 2005) ISBN 0060784237
External links

- [http://www.jambell.com/latin.html Latin Phrases for after dinner conversation (Thanks to Elaine Poole)]
- [http://www.ethnologue.com/show_language.asp?code=lat Ethnologue report for Latin]
- [http://forumromanum.org/literature/index.html Corpus Scriptorum Latinorum] is a comprehensive webography of Latin texts and their translations.
- [http://www.perseus.tufts.edu/ The Perseus Project] has many useful pages for the study of classical languages and literatures, including [http://www.perseus.tufts.edu/cgi-bin/resolveform?lang=Latin an interactive Latin dictionary].
- [http://lysy2.archives.nd.edu/cgi-bin/words.exe words by William whitaker] is a dictionary program online capable of looking up various word forms.
- [http://retiarius.org/ Retiarius.Org] includes a Latin text search engine.
- [http://www.nd.edu/~archives/latgramm.htm Latin-English dictionary and Latin grammar from U of Notre Dame]
- [http://latin-language.co.uk/ Latin language] History of Latin language, Latin texts with English translation and a collection of dictionaries.
- [http://augustinus.eresmas.net/scl/ Societas Circulorum Latinorum] gathers together Latin Circles all over the world.
- [http://www.learnlatin.tk LearnLatin.tk] - Free online course in Latin
- [http://www.latintests.net/ LatinTests.net] - Lets Latin learners test their grammar and vocabulary with self-checking quizzes.
- [http://thelatinlibrary.com/ The Latin Library] contains many Latin etexts
- [http://www.textkit.com/ Textkit] has Latin textbooks and etexts.
- [http://www.websters-online-dictionary.org/definition/Latin-english/ Latin–English Dictionary]: from Webster's Rosetta Edition.
- [http://www.language-reference.com/ Language reference] Cross-foreign-language lexicon powered by its own search engine. All cross combinations between Latin and French, German, Italian, Spanish.
- [http://comp.uark.edu/~mreynold/rhetor.html Rhetor by Gabriel Harvey] was originally published in 1577 and never again reprinted.
- [http://freewebs.com/omniamundamundis omniamundamundis] Latin hypertexts from fourteen ancient Roman authors.
- [http://www.saltspring.com/capewest/pron.htm Pronunciation of Biological Latin, Including Taxonomic Names of Plants and Animals]
- [http://www.yleradio1.fi/nuntii Nuntii Latini (News in Latin)], written and spoken (RealAudio) news in latin. Weekly review of world news in Classical Latin, the only international broadcast of its kind in the world, produced by YLE, the Finnish Broadcasting Company.
- [http://www.tranexp.com:2000/InterTran?url=http%3A%2F%2F&type=text&text=Replace%20Me&from=eng&to=ltt InterTran Latin], Translate from Latin to ENGLISH or vice versa.
- [http://www.latinvulgate.com Latin Vulgate] The Latin and English of the Old & New Testaments in parallel, along with the Complete Sayings of Jesus in parallel Latin and English. Category:Classical languages Category:Ancient languages Category:Fusional languages Category:Languages of Italy Category:Languages of Vatican City als:Latein zh-min-nan:Latin-gí ko:라틴어 ja:ラテン語 simple:Latin language th:ภาษาละติน

Color

Color or colour is the perception of the frequency (or wavelength) of light, and can be compared to how pitch (or a musical note) is the perception of the frequency or wavelength of sound. It is a perception which in humans derives from the ability of the fine structures of the eye to distinguish (usually three) differently filtered analyses of a view. The perception of color is influenced by biology (some people are born seeing colors differently or not at all; see color blindness), long-term history of the observer, and also by short-term effects such as the colors nearby. (This is the basis of many optical illusions.) The science of color is sometimes called chromatics. It includes the perception of color by the human eye, the origin of color in materials, color theory in art, and the physics of color in the electromagnetic spectrum.

Physics of color

The colors of the visible light spectrum.

color	wavelength interval	frequency interval
red	~ 625-740 nm	~ 480-405 THz
orange	~ 590-625 nm	~ 510-480 THz
yellow	~ 565-590 nm	~ 530-510 THz
green	~ 500-565 nm	~ 600-530 THz
cyan	~ 485-500 nm	~ 620-600 THz
blue	~ 440-485 nm	~ 680-620 THz
violet	~ 380-440 nm	~ 790-680 THz
Continuous optical spectrum Image:Spectrum441pxWithnm.png Designed for monitors with gamma 1.5.
Computer "spectrum" Image:Computerspectrum.png The bars below show the relative intensities of the three colors mixed to make the color immediately above.

Color, frequency, and energy of light.

Color	$\lambda \,\!$ /nm	$\nu \,\!$ /10¹⁴ Hz	$\nu_b \,\!$ /10⁴ cm^-1	$E \,\!$ /eV	$E \,\!$ /kJ mol^-1
Infrared	>1000	<3.00	<1.00	<1.24	<120
Red	700	4.28	1.43	1.77	171
Orange	620	4.84	1.61	2.00	193
Yellow	580	5.17	1.72	2.14	206
Green	530	5.66	1.89	2.34	226
Blue	470	6.38	2.13	2.64	254
Violet	420	7.14	2.38	2.95	285
Near ultraviolet	300	10.0	3.33	4.15	400
Far ultraviolet	<200	>15.0	>5.00	>6.20	>598

Electromagnetic radiation is a mixture of radiation of different wavelengths and intensities. When this radiation has a wavelength inside the human visibility range (approximately from 380 nm to 740 nm), it is known as light within the (human) visible spectrum. The light's spectrum records each wavelength's intensity. The full spectrum of the incoming radiation from an object determines the visual appearance of that object, including its perceived color. As we will see, there are many more spectra than color sensations; in fact one may formally define a color to be the whole class of spectra which give rise to the same color sensation, although any such definition would vary widely among different species and also somewhat among individuals intraspecifically. A surface that diffusely reflects all wavelengths equally is perceived as white, while a dull black surface absorbs all wavelengths and does not reflect (for mirror reflection this is different: a proper mirror also reflects all wavelengths equally, but is not perceived as white, while shiny black objects do reflect). The familiar colors of the rainbow in the spectrum—named from the Latin word for appearance or apparition by Isaac Newton in 1671—contains all those colors that consist of visible light of a single wavelength only, the pure spectral or monochromatic colors. The frequencies are approximations and given in terahertz (THz). The wavelengths, valid in vacuum, are given in nanometers (nm). A list of other objects of similar size is available.

Important note

The color table should not be interpreted as a definite list – the pure spectral colors form a continuous spectrum, and how it is divided into distinct colors is a matter of taste and culture. Similarly, the intensity of a spectral color may alter its perception considerably; for example, a low-intensity orange-yellow is brown, and a low-intensity yellow-green is olive-green.

Spectral versus non-spectral colors

Most light sources are not pure spectral sources; rather they are created from mixtures of various wavelengths and intensities of light. To the human eye, however, there is a wide class of mixed-spectrum light that is perceived the same as a pure spectral color. In the table above, for instance, when your computer screen is displaying the "orange" patch, it is not emitting pure light at a fixed wavelength of around 600 nm (which is something most computer screens are unable to do). Rather, it is emitting a mixture of about two parts red to one part green light. Were you to print this page on a color printer, the orange patch on the paper, when lit with white light, would reflect yet another, more continuous spectrum. We cannot see those differences (although many animals can), and the reason has to do with the pigments that make up our color vision cells (see below). A useful quantification of this property is the dominant wavelength, which matches a wavelength of spectral light to a non-spectral source that evokes the same color perception. Dominant wavelength is the formal background for the popular concept of hue. In addition to the many light sources that can appear to be pure spectral colors but are actually mixtures, there are many color perceptions that by definition cannot be pure spectral colors due to desaturation or because they are purples (which are a mixture of red and violet light, from either end of the spectrum). Some examples of necessarily non-spectral colors are the achromatic colors (black, gray and white) and other colors such as pink, tan and magenta. See metamerism (color) for a basic introduction as to why color matching challenges exist.

Physical basis of color

A light wave can be analyzed as a superposition of sine waves, each of which has a specific frequency and wavelength. The eye gives limited information about the relative intensities of these sine waves (but not their phases — the eye is even more blind to phase than the ear, which can detect phase relationships of sounds only in certain very specific contexts). To understand which particular color perception will arise from a particular physical spectrum requires knowledge of the physiology of the retina. The human eye is also insensitive to polarization in most cases (though see Haidinger's brush), whereas some fish and mollusks can perceive it.

Color vision

Though the exact status of color is a matter of current philosophical dispute, color is arguably a psychophysical phenomenon that exists only in our minds. (See Qualia, for some of that dispute.) A "red" apple does not give off "red light", and it is misleading to think of things that we see, or of light itself, as objectively colored at all. Rather, the apple simply absorbs light of various wavelengths shining on it to different degrees, in such a way that the unabsorbed light which it reflects is perceived as red. An apple is perceived to be red only because normal human color vision perceives light with different mixes of wavelengths differently—and we have language to describe that difference. language In 1931, an international group of experts called the Commission Internationale d'Eclairage (CIE) developed a mathematical color model. The premise used by the CIE is that color is the combination of three things: a light source, an object, and an observer. The CIE tightly controlled each of these variables in an experiment that produced the